Velocity ~o~u~~on Laser ~pe~oscopy of Vib~~~nally Excited Cf +: De~~ina~on of ‘ide ~ole~~r Panel Anion
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چکیده
The lowest six vibrational hot bands of CF+ have been measured in a heIium/CsF, discharge by velocity moduiation laser spectroscopy. A total of 56 transitions has been fitted to Dunham expansion for v = O-7, yielding the parameters: we = 1792.6654(18) cm-*, Be = 1.7204176(75) cm-‘, r, = 13.22968(54) cm-‘, and D,, = 62086(30) cm-‘. The rotational temperature of CFC in the plasma is near 650 K and the vibrational temperature is approximately 5200 K.
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